diff --git a/chap1/chap1.pdf b/chap1/chap1.pdf index b2f0825..e05992c 100644 Binary files a/chap1/chap1.pdf and b/chap1/chap1.pdf differ diff --git a/chap1/chap1.tex b/chap1/chap1.tex index 1acd830..b55227d 100644 --- a/chap1/chap1.tex +++ b/chap1/chap1.tex @@ -666,13 +666,13 @@ \subsubsection{The Linear Variational Problem} \begin{equation}\label{key} \begin{aligned} H_{11} &= \Braket{1s | \mathscr{H} | 1s} = -\dfrac{1}{2} + F\Braket{1s| r\cos\theta | 1s} = -\dfrac{1}{2}\\ -H_{12} &= H_{21} = \Braket{1s | \mathscr{H} | 2p_z} = 0 + F\Braket{1s| r\cos\theta | 2p_z} = \dfrac{512 \sqrt{2} \pi }{243}F\\ +H_{12} &= H_{21} = \Braket{1s | \mathscr{H} | 2p_z} = 0 + F\Braket{1s| r\cos\theta | 2p_z} = \dfrac{128 \sqrt{2} \pi }{243}F\\ H_{22} &= \Braket{2p_z | \mathscr{H} | 2p_z} = -\dfrac{1}{8} + F\Braket{2p_z| r\cos\theta | 2p_z} = -\dfrac{1}{8} \end{aligned} \end{equation} -Suppose $ \vb{c} = \mqty(\cos p\\ \sin p) $, +Suppose $ \vb{c} = \mqty(\cos p\\ \sin p) $, with the result of Ex 1.20, we have \begin{equation}\label{key} -p = \dfrac{1}{2}\arctan\dfrac{2H_{12}}{H_{11} - H_{22}} = -\dfrac{1}{2} \tan ^{-1}\qty(\dfrac{2048 \sqrt{2} F}{729}) +p = \dfrac{1}{2}\arctan\dfrac{2H_{12}}{H_{11} - H_{22}} = -\dfrac{1}{2} \arctan \qty(\dfrac{2048 \sqrt{2} F}{729}) \end{equation} thus \begin{equation}\label{key}